关键词:
δ88/86Sr,
标样—样品间插法,
Zr元素外部校正法,
双稀释剂法
Abstract: Because of the development of high-precision stable Sr isotope analytical method, stable Sr isotopes have been paid more attention in recent years. Great progress has been made in studies on supergene geochemistry, paleoenvironment, archaeology, endogenesis, and meteorites. This paper summarizes the key techniques of δ88/86Sr analytical methods. Ion exchange method with Eichrom Sr Specific Resin has been widely used to purify Sr. But this specific resin is expensive and may result in contamination during the chromatographic processes. Thus it could be replaced by cation-exchange resin. MC-ICP-MS and TIMS are the instruments for isotope measurement. Normally, MC-ICP-MS has higher measurement efficiency but slightly lower precision than TIMS. Standard-Sample-Bracketing method, Zr-Empirical-External-Normalization method, and double spike method are used to correct the instrumental mass bias. The Double Spike method may have relatively high measurement precision, but there are only a few studies using this method on MC-ICP-MS. Furthermore, there is no detailed comparison of δ88/86Sr of international standard materials. Therefore, optimizing the analysis process, improving the measurement precision, and more determination of δ88/86Sr of standard materials are necessary for the future studies of stable Sr isotopes.
Key words:
δ88/86Sr,
Standard-Sample-Bracketing,
Zr-Empirical-External-Normalization,
Double Spike